(1-nButyl-1,​5-cyclooctadiene)​dimethylplatinum(II)

m 225

Formula: C14H23Pt

Canonical Smiles: CCCC[C]12=C3[Pt]42(C)(C)C(=C4CC1)CC3

Inchi: InChI=1S/C12H17.2CH3.Pt/c1-2-3-9-12-10-7-5-4-6-8-11-12;;;/h2-3,5,7-9,11H2,1H3;2*1H3;

Inchikey: RAILRAURXLVDTH-UHFFFAOYSA-N

Mass: 386.14

Publication (over 3 years ago)

Authors:

Mirja Enders

Affiliation:

Karlsruhe Institute of Technology, Institute of Organic Chemistry (Stefan Bräse Group)

DOI: 10.14272/RAILRAURXLVDTH-UHFFFAOYSA-N

Characterization

Thumb ptme2 nbu cod  1h

NMR/1H/CDCl3/400

1H-NMR (400 MHz, CDCl3): δ = 4.80-4.64 (m, 3 H, CH), 2.52-2.29 (m, 4 H, CH2), 2.26-2.20 (m, 2 H, CH2), 2.18-2.03 (m, 3 H, CH2), 1.99-1.84 (m, 1 H, CH2), 1.62-1.56 (m, 1 H, CH2), 1.38-1.19 (m, 3 H, CH2), 0.89 (t, 3JHH = 7.2 Hz, 3 H, CH3), 0.69 (s d, 2JPtH = 81.5 Hz, 6 H, CH3) ppm.

DOI: 10.14272/RAILRAURXLVDTH-UHFFFAOYSA-N/NMR/1H/CDCl3/400

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NMR/13C/CDCl3/100

13C-NMR (100 MHz, CDCl3): δ = 120.0 (Cquart), 99.3 (+, s d, 1JPtC = 46.1 Hz, CH), 97.8 (+, s d, 1JPtC = 61.5 Hz, CH), 97.5 (+, s d, 1JPtC = 58.3 Hz, CH), 40.2 (-, CH2), 33.1 (-, CH2), 31.5 (-, CH2), 31.0 (-, CH2), 30.9 (-, CH2), 28.3 (-, CH2), 22.7 (-, CH2), 14.0 (+, CH3CH2), 9.5 (+, PtCH3), 3.5 (+, PtCH3) ppm.

DOI: 10.14272/RAILRAURXLVDTH-UHFFFAOYSA-N/NMR/13C/CDCl3/100


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